### Physics: Thermodynamics

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Thermodynamics (part 1). Thermodynamics (part 2). Thermodynamics (part 3). Thermodynamics (part 4). Thermodynamics (part 5). Macrostates and Microstates. Quasistatic and Reversible Processes. First Law of Thermodynamics/ Internal Energy. More on Internal Energy. Work from Expansion. PV-diagrams and Expansion Work. Proof: U=(3/2)PV or U=(3/2)nRT. Work Done by Isothermic Process. Carnot Cycle and Carnot Engine. Proof: Volume Ratios in a Carnot Cycle. Proof: S (or Entropy) is a valid state variable. Thermodynamic Entropy Definition Clarification. Reconciling Thermodynamic and State Definitions of Entropy. Entropy Intuition. Maxwell's Demon. More on Entropy. Efficiency of a Carnot Engine. Carnot Efficiency 2: Reversing the Cycle. Carnot Efficiency 3: Proving that it is the most efficient. Enthalpy. Heat of Formation. Hess's Law and Reaction Enthalpy Change. Gibbs Free Energy and Spontaneity. Gibbs Free Energy Example. More rigorous Gibbs Free Energy/ Spontaneity Relationship. A look at a seductive but wrong Gibbs/Spontaneity Proof. Stoichiometry Example Problem 1. Stoichiometry Example Problem 2. Limiting Reactant Example Problem 1. Empirical and Molecular Formulas from Stoichiometry. Example of Finding Reactant Empirical Formula. Stoichiometry of a Reaction in Solution. Another Stoichiometry Example in a Solution. Molecular and Empirical Forumlas from Percent Composition. Hess's Law Example. Thermodynamics (part 1). Thermodynamics (part 2). Thermodynamics (part 3). Thermodynamics (part 4). Thermodynamics (part 5). Macrostates and Microstates. Quasistatic and Reversible Processes. First Law of Thermodynamics/ Internal Energy. More on Internal Energy. Work from Expansion. PV-diagrams and Expansion Work. Proof: U=(3/2)PV or U=(3/2)nRT. Work Done by Isothermic Process. Carnot Cycle and Carnot Engine. Proof: Volume Ratios in a Carnot Cycle. Proof: S (or Entropy) is a valid state variable. Thermodynamic Entropy Definition Clarification. Reconciling Thermodynamic and State Definitions of Entropy. Entropy Intuition. Maxwell's Demon. More on Entropy. Efficiency of a Carnot Engine. Carnot Efficiency 2: Reversing the Cycle. Carnot Efficiency 3: Proving that it is the most efficient. Enthalpy. Heat of Formation. Hess's Law and Reaction Enthalpy Change. Gibbs Free Energy and Spontaneity. Gibbs Free Energy Example. More rigorous Gibbs Free Energy/ Spontaneity Relationship. A look at a seductive but wrong Gibbs/Spontaneity Proof. Stoichiometry Example Problem 1. Stoichiometry Example Problem 2. Limiting Reactant Example Problem 1. Empirical and Molecular Formulas from Stoichiometry. Example of Finding Reactant Empirical Formula. Stoichiometry of a Reaction in Solution. Another Stoichiometry Example in a Solution. Molecular and Empirical Forumlas from Percent Composition. Hess's Law Example.

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